HILL MANUFACTURING CO INC -- NO 124 VERSA-TILE GROUT CLEANER -- 6840-00N020165
===================== Product Identification ===================== Product ID:NO 124 VERSA-TILE GROUT CLEANER MSDS Date:12/15/1987 FSC:6840 NIIN:00N020165 === Responsible Party === Company Name:HILL MANUFACTURING CO INC Address:1500 JONESBORO RD City:ATLANTA State:GA ZIP:30315 Country:US Info Phone Num:404-522-8364 Emergency Phone Num:404-522-8364 Preparer's Name:RICK GLISSON CAGE:66086 === Contractor Identification === Company Name:HILL MANUFACTURING CO INC Address:1500 JONESBORO DR Box:City:ATLANTA State:GA ZIP:30315 Country:US Phone:404-522-8364 CAGE:66086 ============= Composition/Information on Ingredients ============= Ingred Name:INGRED 4: AS WITH CHEM, USE W/DUE CARE ACCORDING TO LABEL INSTRUCTIONS & PREC. KEEP OUT OF REACH OF CHILDREN. (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: FOR COMMERCIAL/INDUSTRIAL USE ONLY. RTECS #:9999999ZZ Ingred Name:RESP PROT: ENGINEERING/ADMINISTRATIVE CNTRLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. RTECS #:9999999ZZ Ingred Name:HYDROCHLORIC ACID; (HYDROGEN CHLORIDE) CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: 1-2% OSHA PEL:5 PPM, C ACGIH TLV:5 PPM, C EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PHOSPHORIC ACID CAS:7664-38-2 RTECS #:TB6300000 Fraction by Wt: 7-8% OSHA PEL:1 MG/M3/3 STEL ACGIH TLV:1 MG/M3/3 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUPP DATA: CLEAN-UP IS COMPLETED. STOP SPILL AT SOURCE. DIKE TO PVNT SPREADING. PUMP TO SALVAGE TANK. RTECS #:9999999ZZ Ingred Name:OTHER PREC: CNTNRS RETAIN PROD RESIDUES (VAP, LIQ &/OR SOLID), ALL HAZ PREC GIVEN IN DATA SHEET MUST BE OBSERVED.(ING 5) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES: CAUSES SEVERE DAMAGE AND EVEN BLINDNESS VERY RAPIDLY. SKIN: CAUSES BURNS, POSSIBLE DEEP ULCERATION. INHALATION: OF MIST OR DUST CAN CAUSE DAMAGE TO NASAL AND RESPIRATORY PASSAGES. INGESTION: RES ULTS IN SEVERE DAMAGE TO MUCOUS MEMBRANES AND DEEP TISSUES, CAN RESULT IN DEATH ON PENETRATION TO VITAL AREAS. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN: IMMED FLUSH EXPOS AREA W/H2O FOR AT LEAST 15 MIN, GET MED ATTN. REMOVE CONTAM CLTHG. LAUNDER CONTAM CLTHG BEFORE RE-USE. DISCARD CONTAM SHOES. EYES: IMMED FLUSH W/LRG AMTS OF H2O FOR AT LEAST 15 MIN, LIFTING UPPER & LOWER LIDS OCCASIONALLY. GET IMMED MED ATTN. IF PHYS IS NOT IMMED AVAIL, CONT FLUSHING W/H2O. DO NOT USE CHEM ANTIDOTE. INGEST: DO NOT INDUCE VOMIT. VOMIT WILL CAUSE(SUP DATA) ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, WATER FOG OR CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA W/FULL FACEPIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE AND FULL BODY PROTECTIVE CLOTHING WHEN FIGHTING FIRES. Unusual Fire/Explosion Hazard:ACID REACTS WITH MOST METALS TO RELEASE HYDROGEN GAS WHICH CAN FORM EXPLOSIVE MIXTURES WITH AIR. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILL: COVER CONTAM SURF W/SODIUM BICARBONATE/SODA ASH/SLAKED LIME MIXTURE (50-50). MIX & ADD H2O IF NEC TO FORM SLURRY. SCOOP UP SLURRY & WASH SITE W/SODA ASH SOLN. LRG SPILL: PERSONS NOT WEARI NG PROT EQUIP SHD BE EXCLUDED FROM AREA(SUP DATA) Neutralizing Agent:SODIUM BICARBONATE, SODA ASH, SLAKED LIME. ====================== Handling and Storage ====================== Handling and Storage Precautions:ALWAYS STORE UNUSED PORTION IN ORIGINAL CNTNR W/CAP SECURE. NEVER STORE IN UNLABELED/IMPROPERLY LBLD CNTNR. Other Precautions:ADDTN TO H2O RELS HEAT WHICH CAN RSLT IN VIOLENT BOILING & SPATTERING. ALWAYS ADD SLOWLY & IN SMALL AMTS. NEVER USE HOT H2O. NEVER ADD H2O TO ACIDS. ALWAYS ADD ACIDS TO H2O. CNTNRS OF MATL MAY BE HAZ WHEN EMPTIED.SINCE EMPTIED (ING 4) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV OF PROD/ANY COMPONENT IS EXCEEDED, A NIOSH/ MSHA JOINTLY APPRVD AIR SUP RESP IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CNTRL. OSHA REGS ALSO PERMIT OTHER NIOSH/MSHA RESP UNDER SPECIFIED CND TNS. (SEE YOUR SFTY EQUIP SUP).(ING 7) Ventilation:PROVIDE SUFFICIENT MECH (GEN &/OR LOCAL EXHST) VENT TO MAINTAIN EXPOSURE BELOW TLV (S). Protective Gloves:NEOPRENE GLOVES, OR NATURAL RUBBER. Eye Protection:CHEM WORK GOG & FULL LGTH FACESHLD Other Protective Equipment:IMPERVIOUS CLOTHING & BOOTS TO PREVENT SKIN CONTACT. EMERGENCY EYEWASH AND DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC: FURTHER DAMAGE TO THROAT. DILUTE BY GIVING H2O. GIVE MILK OF MAGNESIA. KEEP WARM, QUIET. GET MED ATTN IMMED. INHAL: IF AFFECTED, REMOVE INDIV TO FRESH AIR. IF BRTHG IS DFCLT, ADMIN O2. IF BRTHG HAS STOPPED GIVE ARTF RESP. KEEP PERSON WARM, QUIET & GET MED ATTN. SPILL PROC: OF SPILL UNTIL (ING 3) ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:230F,110C Vapor Pres:28.00 Vapor Density:1.2 Spec Gravity:1.160 pH:<2 Evaporation Rate & Reference:2.00 (N-BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR BLUE LIQUID WITH CHERRY ODOR. Percent Volatiles by Volume:70 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG ALKALIES, ALKALI METALS. Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS, HYDROGEN CHLORIDE, ACID VAPORS, ETC. ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL SPILL: FLUSH DOWN DRAIN W/LRG AMTS OF H2O I/A/W LOCAL, STATE AND FEDERAL REGULTIONS. LARGE SPILL: COLLECT AND ADD SLOWLY TO LRG VOL OF AGITATED SOLN OF SODA ASH & SLAKED LIME. ADD NEUT SOLN TO E XCESS RUNNING H2O I/A/W LOCAL, STATE & FED REGS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.