U S AIRGAS INC. -- ARGON,COMPRESSED;ARGON,REFRIGERATED LIQUID -- 6830-00-169-0779
===================== Product Identification ===================== Product ID:ARGON,COMPRESSED;ARGON,REFRIGERATED LIQUID MSDS Date:01/01/1995 FSC:6830 NIIN:00-169-0779 === Responsible Party === Company Name:U S AIRGAS INC. Address:100 MATSONFORD ROAD SUITE 550 City:RADNOR State:PA ZIP:19087 Country:US Info Phone Num:610-687-5253 Emergency Phone Num:800-424-9300(CHEMTREC) Preparer's Name:NONE CAGE:0MN39 === Contractor Identification === Company Name:AIRGAS INC Address:100 MATSONFORD RD SUITE 550 Box:City:WAYNE State:PA ZIP:19087 Country:US Phone:215-687-5253 CAGE:0MN39 ============= Composition/Information on Ingredients ============= Ingred Name:ARGON CAS:7440-37-1 RTECS #:CF2300000 Fraction by Wt: >99.9% Other REC Limits:NONE RECOMMENDED ACGIH TLV:ASPHYXIANT; 9596 Ingred Name:TOTAL NITROGEN AND OXYGEN Fraction by Wt: <0.1% Other REC Limits:NONE RECOMMENDED ACGIH TLV:ASPHYXIANT; 9596 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO DATA AVAILABLE. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL:SYMPTOMS OF ASPHYXIA.SKIN:NO ADVERSE EFFECTS FROM GAS.LIQ MAY CAUSE FROSTBITE W/REDNESS,TINGLING,PAIN/NUMBNESS.SEVERE CASE-SKIN BECOME HARD,WHITE,DEVELOP BLISTERS.EYE:NO ADVERSE EFFECTS FROM GAS .LIQ MAY CAUSE FROSTBITE W/REDNESS,PAIN,BLURR VISION.INGEST:UNLIKELY.LIQ INGEST FROSTBITE DMG TO LIPS/MOUTH/MUC MEMBRANE Explanation of Carcinogenicity:PER MSDS:CARCINOGEN STATUS:NONE. Effects of Overexposure:INHAL:UNCONSC,RAPID RESP/PULSE,AIR HUNGER,DIZZ,REDUCED AWARENESS,TIGHT IN HEAD,TINGLING SENS,INCOORD,FAULTY JUDGEMENT,EMOTIONAL INSTABILITY,RAPID FTG.NAU,VOMIT,COLLAPSE,UNCONSC,CONVUL,DEEP COMA,DEATH. SKIN:FROSTBITE,RED,TINGLING,PAIN,NUMBNESS,HARD,WHITE,BLISTERS.EYE:F ROSTBITE,RED,PAIN,BLUR VISION.INGEST:FROSTBITE DMG. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. TARGET EFFECTS:SIMPLE ASPHYXIANT. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR IMMED.STOP BREATH GIVE ART RESP.ADMIN OXY IF AVAILABLE.TREAT SYMPT/SUPP.SKIN:GAS-UNLIKELY EMERG TREAT WILL BE REQUIRED.ADVERSE EFFECTS OCCUR GET MED ATTN.EYE:GAS-UNLIKELY EME RG TREATMENT WILL BE REQUIRED.CONTACT W/LIQ WASH W/LG AMTS OF WARM WATER APPROX 15-20MINS.INGEST:UNLIKELY EMERG TREAT WILL BE REQUIRED.ADVERSE EFFECTS OCCUR TREAT SYMTP/SUPP.IN ALL CASES GET MED (SUP) ===================== Fire Fighting Measures ===================== Flash Point:NP Lower Limits:NP Upper Limits:NP Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,OR HALON.LG FIRES:USE WATERSPRAY, FOG, OR STD FOAM. Fire Fighting Procedures:MOVE CNTNR FROM FIRE AREA IF POSSIBLE.STAY AWAY FROM STORAGE TK ENDS.COOL FIRE-EXPO CNTNR W/WATER FROM SIDE TIL WELL AFT FIRE OUT.W/D IMMED IF RISING SOUND(SUP) Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPO TO HEAT/FLAME. CYLINDER MAY EXPLODE IN HEAT/FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:STOP LEAK W/O RISK.KEEP UNNECESSARY PEOPLE AWAY;ISOLATE HAZ AREA/DENY ENTRY.VENTILATE CLOSED SPACES BEFORE ENTERING. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:OBSERVE ALL FED/STATE/LOC REGS WHEN STORING SUBSTANCE.FOR ASSISTANCE CONTACT DIST DIR OF EPA.STORE IAW 29 CFR 1910.101. Other Precautions:DO NOT PERMIST PHYSICAL DMG/OVERHEATING OF CNTNRS.CONTENTS UNDER PRESSURE;CNTNRS MAY VIOLENTLY RUPTURE & TRAVEL CONSIDERABLE DISTANCE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SPEC RESP SELECTED MUST BE BASED ON CONTMAIN LEVELS FOUND IN WORKPLACE,NOT EXCEED WORK LIMITS OR RESP,JOINTLY APPROVED BY NIOSH/MSHA.SUPP-AIR RESP IN PRESS DEMAND/+PRESS MODE;SCBA;SCBA W/FULL FCPIECE IN PRESS DEMAND/+PRESS MODE;ETC. Ventilation:PROVIDE GENERAL DILUTION VENTILATION. Protective Gloves:FULL PROTECTIVE COLD INSULTATING GLOVES. Eye Protection:NOT REQUIRED BUT RECOMMENDED. Other Protective Equipment:GAS-PROTECTIVE CLOTH NOT REQUIRED.LIQ-WEAR APPROPRIATE CLOTH/EQPMT PREVENT SKIN FREEZING.LIQ-SPLASH-PROOF GOGG,FCSHIELD. Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN.EYEWASH FOUNTIAN,QUICK DRENCH SHOWER W/IN IMMED WORKAREA FOR EMERG USE. Supplemental Safety and Health SPEC GRAVITY(LIQ):1.40@-186C. FIREFIGHT:FROM VENT SAF DEVICE/DISCOLORATION OF STORAGE TK DUE TO FIRE.USE AGENT SUITABLE FOR TYP OF FIRE.COOL CNTN W/FLOODING QUANT OF WATER.APPLY FROM AS FAR DISTANCE A S POSSIBLE.AVOID BREATH TOXIC VAP;KEEP UPWIND.STOP LEAK W/O RISK. 1STAID:ATTN.NO SPECIFIC ANTIDOTE.TREAT SYMPT/SUPP. ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:-303F,-186C Melt/Freeze Pt:M.P/F.P Text:-308F,-189C Decomp Temp:Decomp Text:NP Vapor Pres:NP Vapor Density:1.784G/L Spec Gravity:1.38@21.1C,1ATM pH:NP Evaporation Rate & Reference:NP Solubility in Water:3.36ML/100G @20C Appearance and Odor:ODORLESS, TASTELESS, COLORLESS INERT GAS. Percent Volatiles by Volume:NP Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO DATA AVAILABLE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE HAZARDOUS. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVER ALL FED/STATE/LOC REGS WHEN DISPO SUBSTANCE.FOR ASSISTANCE CONTACT DIST DIR OF EPA.VENT SLOWLY TO/ALLOW TO EVAPORATE IN WELL-VENTI OUTDOOR LOCATION REMOTE FROM PERSONNEL WORKAREA/BLDG AIR INT AKES. 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